Vertical interpenetration of 1D water column and 1D coordination polymer chain

被引:7
|
作者
Chen, Shuo-Ping [1 ]
Yuan, Xuan [1 ]
Pan, Ling-Ling [1 ]
Yuan, Liang-Jie [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
关键词
vertical interpenetration; 1D water column; 1D coordination polymer chain;
D O I
10.1007/s10904-008-9215-y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Hydrothermal reaction of 1-amino-1-phenylmethane-1,1-diphosphonic acid (APhMDPH(4)), ZnO and 2,2'-bipyridyl (2,2-bipy) affords a novel zinc phosphonate compound, i.e. Zn-3(L1H)(2)(2,2'-bipy)(3)center dot 18H(2)O (1), in which the phosphonate ligand, L1H4, is generated via an in situ concentration reaction. This compound is a one-dimensional (1D) zigzag coordination polymer chain and a huge, complex 1D water column. The 1D water column and the 1D coordination polymer chain are joined together to form a vertical interpenetrating network, which is reported for the first time.
引用
收藏
页码:384 / 390
页数:7
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