The pH as a key parameter in the choice between coagulation and electrocoagulation for the treatment of wastewaters

被引:139
|
作者
Canizares, Pablo [1 ]
Jimenez, Carlos [1 ]
Martinez, Fabiola [1 ]
Rodrigo, Manuel A. [1 ]
Saez, Cristina [1 ]
机构
[1] Univ Castilla La Mancha, Fac Ciencias Quim, Dept Chem Engn, Ciudad Real 13005, Spain
关键词
Aluminum; Electrocoagulation; Coagulation; Door-manufacturing wastes; O/W emulsions; TEXTILE WASTE-WATER; NATURAL ORGANIC-MATTER; ALUMINUM-CHLORIDE; FLOCCULATION; SPECIATION; SALTS;
D O I
10.1016/j.jhazmat.2008.06.073
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work, it is studied the influence of the pH of the waste in the coagulation with aluminum by conventional and electrochemical dosing. To do that, the speciation of aluminum as a function of the pH has been characterized, and this information has been used to interpret the results obtained in the treatments (by both coagulation methods) of a synthetic oil-in-water emulsion and an actual effluent of a door-manufacturing factory. Results show that a simple change in the pH of the wastes can result in a significant change in the efficiency of the coagulation process, and that if the same pH conditions are found at the end of the treatment, the efficiencies of the solution-dosing and of the electrochemical dosing technologies are very similar. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:158 / 164
页数:7
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