(2,2-bipyridyl)bis(η5-pentamethylcyclopentadienyl)strontium(II)

被引:4
|
作者
Kazhdan, Daniel [1 ,2 ]
Hu, Yung-Jin [3 ]
Kokai, Akos [3 ]
Levi, Zerubba [3 ]
Rozenel, Sergio [3 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Div Chem Sci, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Coll Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1107/S1600536808024677
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Sr(C10H15)(2)(C10H8N2)], the Sr-N distances are 2.624 (3) and 2.676 (3) angstrom, the Sr center dot center dot center dot Cp ring centroid distances are 2.571 and 2.561 angstrom and the N-C-C-N torsion angle in the bipyridine ligand is -2.2 (4)degrees. Interestingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7 (1)degrees.
引用
收藏
页码:M1134 / U331
页数:13
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