Novel pyridine catalysed reactions of dimethyl acetylenedicarboxylate (DMAD) and arylmethylidenemalononitriles: a stereoselective synthesis of highly substituted buta-1,3-dienes

被引：26

作者：

Nair, V ^{[1
]}

Devi, BR

Vidya, N

Menon, RS

Abhilash, N

Rath, NP

机构：

[1] CSIR, Div Organ Chem, Trivandrum 695019, Kerala, India

[2] Univ Missouri, Dept Chem, St Louis, MO 63121 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 16期

关键词：

pyridine; dimethyl acetylenedicarboxylate; dipoles;

D O I：

10.1016/j.tetlet.2004.02.132

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A pyridine catalysed addition of dimethyl acetylenedicarboxylate to various arylmethylidenemalononitriles to afford highly substituted 1,3-butadienes with complete stereoselectivity is described. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：3203 / 3205

页数：3

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