Carbonyl[hydrotris(3,5-dimethylpyrazol-1-yl)-borato]copper(I) acetonitrile solvate

被引：9
|
作者：
Blake, AJ [1 ]
Carling, DA [1 ]
George, MW [1 ]
Hubberstey, P [1 ]
Garcia, RL [1 ]
Wilson, C [1 ]
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S1600536801021730
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu(C15H22BN6)(CO)].C2H3N, crystallizes as neutral [Tp*Cu(CO)] {[Tp*](-) = hydrotris(3,5-dimethylpyrazol-1-yl)borate} molecular units and non-coordinated acetonitrile molecules. The distorted tetrahedral coordination geometry of the copper(I) centre comprises the three N atoms of the [Tp*](-) anion [Cu-N 2.033 (2)-2.054 (2) Angstrom] and the C atom of the carbon monoxide molecule [Cu-C 1.785 (4) Angstrom].
引用
收藏
页码：m41 / m42
页数：2
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