A Modified Recipe and Variations for the Briggs-Rauscher Oscillating Reaction

被引:20
|
作者
Furrow, Stanley D. [1 ]
机构
[1] Penn State Univ, Dept Chem, Penn State Berks Coll, Reading, PA 19610 USA
关键词
First-Year Undergraduate/General; Demonstrations; Physical Chemistry; Textbooks/Reference Books; Electrolytic/Galvanic Cells/Potentials; Kinetics; Mechanisms of Reactions; Oxidation/Reduction; DIIODOMALONIC ACID; SYSTEM; MODEL;
D O I
10.1021/ed200764r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A modified recipe for the Briggs-Rauscher oscillating reaction is suggested. The modified recipe, [H2SO4] = 0.10 M, [KIO3] = 0.020 M, [NaIO4] = 0.00062 M, [malonic acid] = 0.050 M, [MnSO4] = 0.0067 M, [H2O2] = 1.0 M with 0.01% starch, turns blue almost immediately, then oscillations start with two "slow" (similar to 25 s) cycles, then settle into regular approximately 12-15 s cycles. Oscillations end with a clear solution, avoiding cleanup of solid iodine resulting from the "standard" recipe, so that only neutralization of excess acid is needed before disposal. Effects of concentration variations are presented.
引用
收藏
页码:1421 / 1424
页数:4
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