Modulation of Eu(III) and Yb(III) Luminescence Using a DTE Photochromic Ligand

被引：23

作者：

He, Xiaoyan ^{[1
]}

Norel, Lucie ^{[1
]}

Hervault, Yves-Marie ^{[1
]}

Metivier, Remi ^{[2
]}

D'Aleo, Anthony ^{[3
]}

Maury, Olivier ^{[4
]}

Rigaut, Stephane ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes, Campus Beaulieu, F-35042 Rennes, France

[2] ENS Cachan, CNRS, UMR 8531, PPSM, F-94235 Cachan, France

[3] Aix Marseille Univ, CNRS, UMR 7325, CINaM, Campus Luminy,Case 913, F-13288 Marseille, France

[4] Univ Claude Bernard Lyon 1, Lab Chim, ENS Lyon, CNRS,UMR 5182,Univ Lyon, F-69342 Lyon, France

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 24期

关键词：

EUROPIUM(III) COMPLEX; TUNABLE PHOTOCHROMISM; LANTHANIDE COMPLEXES; ELECTRON-TRANSFER; CHARGE-TRANSFER; DIARYLETHENE; FLUORESCENCE; DERIVATIVES; SWITCHES; BEHAVIOR;

D O I：

10.1021/acs.inorgchem.6b01797

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work, we show that a dithienylethene (DTE) modified dipicolinic amide ligand can be a versatile tool to modulate Eu(III) and Yb(III) luminescence using light as an external stimulus. The nature of the modulation depends on the lanthanide emitter: with the europium ion, the DTE ligand quenches the red luminescence upon ring closure, whereas with the ytterbium ion, ring closure can be used to turn on the luminescence in the NIR range.

引用

页码：12635 / 12643

页数：9

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