Synthesis and characterization of novel conducting 1,5-naphthalenediamine-aniline copolymer

被引：4
|
作者：
Ramachandran, Rajamanickam [2 ]
Kathiravan, R. [1 ]
Rani, Mannangatty [1 ]
Kabilan, Senthamaraikannan [1 ]
Jeong, Yeon Tae [2 ]
机构：
[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India
[2] Pukyong Natl Univ, Dept Image Sci & Engn, Pusan 608737, South Korea
来源：
SYNTHETIC METALS | 2012年 / 162卷 / 17-18期
关键词：
1,5-Naphthalenediamine; Aniline; Copolymer; Semiconductor; Morphology; CARBON NANOTUBES; POLYANILINE; POLYMER;
D O I：
10.1016/j.synthmet.2012.06.011
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The poly(1,5-naphthalenediamine-co-aniline) has been synthesized by chemical oxidative polymerization method in an acidic medium. The copolymer with different counter ions (HCL, H2SO4, CH3COOH and HNO3) has been investigated. The newly synthesized copolymers were characterized by UV-visible, FT-IR, fluorescence, H-1 NMR, cyclic voltammetry, TGA and SEM studies. Conductivity studies of the copolymer with various counter ions were also carried out and found to be in the region of semiconductor. Morphological study revealed that the copolymer formed into hollow spheres with smooth surface. Moreover, a detailed reaction mechanism has been postulated for the formation of target copolymer. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：1636 / 1642
页数：7
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