We give details of the analysis of critical properties of spin-gap phases in one-dimensional lattice electron models. In Tomonaga-Luttinger (TL) liquid theory, the spin-gap instability occurs when the backward scattering changes from repulsive to attractive. This transition point is, shown to be equivalent to that of the level-crossing of the singlet and triplet excitation spectra, using the c=1 conformal field theory and the renormalization group. Based on this notion, the transition point between the TL liquid and the spin-gap phases can be determined with high-accuracy, from the numerical data of finite-size clusters. We also discuss the boundary conditions and discrete symmetries to extract these excitation spectra. This technique is applied to the extended Hubbard model, the t-J model, and the t-J-J' model, and their phase diagrams are obtained. We also discuss the relation between our results and analytical solutions in weak-coupling and low-density limits.