An unprecedented 1D zigzag chain alkaline earth metal derivative {[Ba(DMF)3(H2O)2][Ba(DMF)4]2(P2W18O62)}n containing Dawson heteropolyanion

被引：0
|
作者：
Wang, Jing Ping [1 ]
Ma, Jian Ru [1 ]
Niu, Jing Yang [1 ]
机构：
[1] Henan Univ, Sch Chem & Chem Engn, Kaifeng 475001, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2006年 / 17卷 / 06期
关键词：
polyoxometalate; crystal structure; Dawson structure;
D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unprecedented 1D zigzag chain alkaline earth metal derivative, {[Ba(DMF)(3) (H2O)(2)][Ba(DW)(4)](2)(P2W18O62)}(n), (DMF=N, N-dimethyl formamide) containing Dawson heteropolyanion has been successfully synthesized and characterized by X-ray crystallography. Two barium cations bridged by three DMF ligands in parallel combination with the Dawson-type heteropolyanion [P2W18O62](6-) and then the resulting subunits {[Ba(DMF)(4)](2)(P2W18O62)}(2+) are alternately linked together via another [Ba(DMF)(3)(H2O)(2)](2+) ions, constructing a 1D zigzag chain architecture.
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页码：817 / 820
页数：4
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