EPR and optical absorption studies of Cu2+ doped L-histidinium dihydrogen phosphate-phosphoric acid single crystal

被引：6
|
作者：
Prabakaran, R. [1 ]
Sheela, K. Juliet [1 ]
Rosy, S. Margret [1 ]
Krishnan, S. Radha [2 ]
Shanmugam, V. M. [2 ]
Subramanian, P. [1 ]
机构：
[1] Deemed Univ, Gandhigram Rural Inst, Dept Phys, Dindigul 624302, Tamil Nadu, India
[2] Cent Electrochem Res Inst, CSIR, Karaikkudi 630006, Tamil Nadu, India
来源：
PHYSICA B-CONDENSED MATTER | 2014年 / 434卷
关键词：
EPR; Single crystal; Optical absorption studies; Cu2+; Spin Hamiltonian; GROWTH;
D O I：
10.1016/j.physb.2013.11.019
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The EPR spectra of Cu2+ in L-histidinium dihydrogen phosphate phosphoric acid at room temperature reveal the presence of two magnetically inequivalent Cu2+ sacs in the lattice. The principal values of the g- and A-tensors indicate existence of rhombic symmetry around the Cu2+ ion. From the direction cosines of the principal values of the g- and A-tensors, the locations of Cu2+ in the lattice have been identified as substitutional sites. Optical absorption study shows four bands confirm the rhombic symmetry. Photoluminescence study also confirms the rhombic symmetry around the ions. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：155 / 158
页数：4
相关论文
共 50 条
  • [31] EPR AND OPTICAL-ABSORPTION STUDIES OF VO2+ AND CU2+ IONS DOPED IN LIHSO4 SINGLE-CRYSTALS
    MAURYA, BP
    PUNNOOSE, A
    SINGH, RJ
    SOLID STATE COMMUNICATIONS, 1995, 94 (03) : 231 - 235
  • [32] An EPR study of Cu2+ doped sodium hydrogen oxalate monohydrate single crystal
    Karabulut, B
    Bulut, A
    Tapramaz, R
    SPECTROSCOPY LETTERS, 1999, 32 (04) : 571 - 579
  • [33] An EPR study of Cu2+ doped sodium hydrogen oxalate monohydrate single crystal
    Ondokuz Mayis University, Faculty of Arts and Sciences, Department of Physics, 55139 Samsun, Turkey
    Spectrosc Lett, 4 (571-579):
  • [34] Growth and characterization of L-histidinium fumarate fumaric acid monohydrate single crystal: A promising second and third order nonlinear optical material
    Mohamed, M. Peer
    Sudha, S.
    Jayaprakash, P.
    Vinitha, G.
    Nageshwari, M.
    Sangeetha, P.
    Kumari, C. Rathika Thaya
    Caroline, M. Lydia
    CHINESE JOURNAL OF PHYSICS, 2019, 60 : 581 - 597
  • [35] Single crystal EPR and optical studies of Cu(II) doped zinc ammonium phosphate hexahydrate: A case of rhombic distortion
    Poonguzhali, E
    Srinivasan, R
    Ravikumar, RVSSN
    Chandrasekhar, AV
    Reddy, BJ
    Reddy, YP
    Rao, PS
    PHYSICA SCRIPTA, 2002, 66 (05) : 391 - 394
  • [36] EPR, Optical Absorption and Superposition Model Study of Fe3+-Doped Ammonium Dihydrogen Phosphate Single Crystals
    Ram Kripal
    Sangita Pandey
    Applied Magnetic Resonance, 2010, 38 : 471 - 484
  • [37] EPR, Optical Absorption and Superposition Model Study of Fe3+-Doped Ammonium Dihydrogen Phosphate Single Crystals
    Kripal, Ram
    Pandey, Sangita
    APPLIED MAGNETIC RESONANCE, 2010, 38 (04) : 471 - 484
  • [38] EPR and Optical Absorption Study of Cu2+ Ions Doped in Potassium Hexaaquazinc (II) Sulphate (PHZS) Single Crystals
    Ram Kripal
    Madan Gopal Misra
    Prashant Dwivedi
    Applied Magnetic Resonance, 2012, 42 : 251 - 267
  • [39] EPR and optical absorption studies of VO2+ doped L-arginine phosphate monohydrate single crystals -: part I
    Mary, PAA
    Dhanuskodi, S
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2001, 57 (12) : 2345 - 2353
  • [40] EPR and Optical Absorption Study of Cu2+ Ions Doped in Potassium Hexaaquazinc (II) Sulphate (PHZS) Single Crystals
    Kripal, Ram
    Misra, Madan Gopal
    Dwivedi, Prashant
    APPLIED MAGNETIC RESONANCE, 2012, 42 (02) : 251 - 267
12345