Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

被引：26
|
作者：
Ohgo, Y [1 ]
Chiba, Y
Hashizume, D
Uekusa, H
Ozeki, T
Nakamura, M
机构：
[1] Toho Univ, Sch Med, Dept Chem, Ota Ku, Tokyo 1438540, Japan
[2] Toho Univ, Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748510, Japan
[3] Toho Univ, Grad Sch Sci, Div Biomol Sci, Funabashi, Chiba 2748510, Japan
[4] RIKEN, Mol Characterizat Team, Wako, Saitama 3510198, Japan
[5] Tokyo Inst Technol, Dept Chem & Mat Sci, Tokyo 1528551, Japan
[6] Toho Univ, Grad Sch Sci, Div Chem, Funabashi, Chiba 2748510, Japan
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 18期
关键词：
D O I：
10.1039/b601412g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel spin transition between S=5/2 and S=3/2 has been observed for the first time in five-coordinate, highly saddled iron(III) porphyrinates by EPR and SQUID measurements at extremely low temperatures.
引用
收藏
页码：1935 / 1937
页数：3
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