catena-Poly[[bis(nitrato-κ2O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ2N4:N4′]

被引：6
|
作者：
Huang, Hua-Ming [1 ]
Ju, Feng-Yang [1 ]
Wang, Jian-Ge [1 ]
Qin, Jian-Hua [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536808041202
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(NO3)(2)(C6H6N4S4)](n), the Cu-II atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2 '-[1,2-ethanediylbis(thio)]-bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octahedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2 '-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands link the Cu-II centres into a one-dimensional chain. The chains are interconnected via intermolecular S center dot center dot center dot O interactions [3.044 ( 4) and 3.084 (5) angstrom] and weak C-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional supramolecular structure.
引用
收藏
页码：M80 / U856
页数：12
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