Tetraethylammonium tricarbonylchlorido(isoquinoline-1-carboxylato-κ2N,O)technetate(I)

被引：0
|
作者：
Schmalle, Helmut W. [1 ]
Alberto, Roger [1 ]
机构：
[1] Univ Zurich, Inst Anorgan Chem, CH-8057 Zurich, Switzerland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
基金：
瑞士国家科学基金会;
关键词：
D O I：
10.1107/S160053680802713X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, (C8H20N)[Tc(C10H6NO2) Cl(CO)(3)], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetraethylammonium cations. The Tc atoms have slightly distorted octahedral coordination geometries, and they are linked with the cations by intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen-bonding contacts, forming two-dimensional columns, which lie approximately parallel to (001) in the crystal structure. The isochinolate (isoquinoline-1-carboxylate) ligands link the columns by partial pi-pi stacking [centroid-centroid distance 4.3733 (11) angstrom], forming a three-dimensional network structure.
引用
收藏
页码：M1213 / U1011
页数：17
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