Effect of the Molecular Architecture of Side Radicals on the Optical Properties of Comb-Shaped Polymers

被引：2
|
作者：
Kolbina, G. F. [1 ]
Kononov, A. I. [2 ]
Shtennikova, I. N. [1 ]
Grishchenko, A. E. [2 ]
机构：
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[2] St Petersburg State Univ, Fock Inst Phys, St Petersburg 198504, Russia
来源：
POLYMER SCIENCE SERIES C | 2010年 / 52卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
Polymer Science Series; Main Chain; Monomer Unit; Intrinsic Viscosity; Optical Anisotropy;
D O I：
10.1134/S1811238210010091
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The optical properties of four comb-shaped polymers of the methacrylic series with different optically anisotropic groups in side chains are studied by the methods of flow birefringence and viscometry. The experimental values of the optical anisotropy are compared with theoretical estimates calculated in terms of the additivity principle of polarizabilities of valence bonds. It is shown the optical properties of comb-shaped polymers significantly depend on the position (even or odd) of optically anisotropic side groups relative to the main chain.
引用
收藏
页码：79 / 82
页数：4
相关论文
共 50 条
  • [41] Chromatic changes in the blends of electroactive polymers with comb-shaped flexible polymers
    Kim, MS
    Levon, K
    MACROMOLECULAR SYMPOSIA, 1997, 116 : 73 - 104
  • [42] Molecular Mobility of a Comb-Shaped Copolymethacrylate with Chalcone Chromophore-Containing Side Groups
    Nikonorova, N. A.
    Smirnov, N. N.
    Nosova, G. I.
    Solovskaya, N. A.
    Yakimansky, A. V.
    POLYMER SCIENCE SERIES A, 2010, 52 (12) : 1301 - 1310
  • [43] Molecular mobility of a comb-shaped copolymethacrylate with chalcone chromophore-containing side groups
    N. A. Nikonorova
    N. N. Smirnov
    G. I. Nosova
    N. A. Solovskaya
    A. V. Yakimansky
    Polymer Science Series A, 2010, 52 : 1301 - 1310
  • [44] Local dielectric relaxation and formation of a molecular network in photosensitive comb-shaped polymers and copolymers
    Afanas'eva, N.V.
    Borisova, T.I.
    Lebedeva, G.K.
    Ivanova, V.N.
    Shevelev, V.A.
    Kudryashov, V.V.
    Nuantong Kongtiao/HV and AC, 1998, 28 (06): : 2083 - 2088
  • [45] Local dielectric relaxation and formation of a molecular network in photosensitive comb-shaped polymers and copolymers
    Afanas'eva, NV
    Borisova, TI
    Lebedeva, GK
    Ivanova, VN
    Shevelev, VA
    Kudryavtsev, VV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1998, 40 (12): : 2083 - 2088
  • [46] Viscoelastic properties of comb-shaped ring polystyrenes
    Yuya Doi
    Jinya Kitamura
    Takashi Uneyama
    Yuichi Masubuchi
    Atsushi Takano
    Yoshiaki Takahashi
    Yushu Matsushita
    Polymer Journal, 2022, 54 : 1267 - 1277
  • [47] Effect of the processes of orientation of nonlinear optical fragments of a side chain in comb-shaped polymers of the methacrylic series on the second-harmonic generation in thin films
    Lebedeva, GK
    Sokolova, IM
    Ivanova, VN
    Lukoshkin, VA
    Loretsyan, NL
    Kudryavtsev, VV
    PHYSICS OF THE SOLID STATE, 2001, 43 (04) : 783 - 787
  • [48] Effect of the processes of orientation of nonlinear optical fragments of a side chain in comb-shaped polymers of the methacrylic series on the second-harmonic generation in thin films
    G. K. Lebedeva
    I. M. Sokolova
    V. N. Ivanova
    V. A. Lukoshkin
    N. L. Loretsyan
    V. V. Kudryavtsev
    Physics of the Solid State, 2001, 43 : 783 - 787
  • [49] Viscoelastic properties of comb-shaped ring polystyrenes
    Doi, Yuya
    Kitamura, Jinya
    Uneyama, Takashi
    Masubuchi, Yuichi
    Takano, Atsushi
    Takahashi, Yoshiaki
    Matsushita, Yushu
    POLYMER JOURNAL, 2022, 54 (11) : 1267 - 1277
  • [50] UNUSUAL ELECTRO-OPTICAL PROPERTIES OF COMB-SHAPED LIQUID CRYSTALLINE POLYACRYLATES
    Bobrovsky, Aleksey Yu.
    Boiko, Natalya I.
    Shibaev, Valery P.
    LIQUID CRYSTALS AND THEIR APPLICATION, 2022, 22 (03): : 71 - 80
12345