Separation of cobalt and nickel by solvent extraction with two mutually immiscible ionic liquids

被引：57
|
作者：
Wellens, Sil [1 ]
Thijs, Ben [2 ]
Moller, Claudia [2 ]
Binnemans, Koen [1 ]
机构：
[1] KU Leuven Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium
[2] Umicore, Res & Dev Grp, Competence Area Recycling & Extract Technol, B-2250 Olen, Belgium
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 24期
关键词：
CHLORIDE SOLUTIONS; MIXTURES; PHOSPHONIUM; PALLADIUM(II); LANTHANIDES; METALS; GOLD;
D O I：
10.1039/c3cp50819f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The proof-of-principle for the separation of metals by solvent extraction using two mutually immiscible ionic liquids is given. Cobalt was extracted from the ionic liquid 1-ethyl-3-methylimidazolium chloride to the ionic liquid trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate. A distribution ratio of 44 was obtained. Cobalt could be selectively separated from nickel, with a separation factor of 207. The extraction mechanism was elucidated using UV-VIS absorption measurements. The mutual solubility between the two ionic liquids was determined by H-1 NMR. Processing steps such as washing, stripping and regeneration of the ionic liquid phases are discussed.
引用
收藏
页码：9663 / 9669
页数：7
相关论文
共 50 条
  • [21] Separation of copper, nickel and cobalt in sulphate and chloride solutions by solvent extraction
    Yang, JY
    Li, JP
    Zhong, YG
    HYDROMETALLURGY 2003 PROCEEDINGS, VOLS 1 AND 2: VOL 1: LEARNING AND SOLUTION PURIFICATION, 2003, : 1993 - 1998
  • [22] Studies on separation of cobalt and nickel by non-equilibrium solvent extraction
    Qian Dong
    Wang Kaiyi
    Wang Hong'en
    PROCEEDINGS OF THE CHINA ASSOCIATION FOR SCIENCE AND TECHNOLOGY, VOL 2, NO 1, 2006, : 307 - 311
  • [23] Separation of nickel, cobalt and copper by solvent extraction with P204
    Qian, D
    Wang, KY
    Cai, CL
    Pan, CY
    Tang, YG
    Jiang, JZ
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2001, 11 (05) : 803 - 805
  • [24] A continuous ionic liquid extraction process for the separation of cobalt from nickel
    Wellens, Sil
    Goovaerts, Remi
    Moeller, Claudia
    Luyten, Jan
    Thijs, Ben
    Binnemans, Koen
    GREEN CHEMISTRY, 2013, 15 (11) : 3160 - 3164
  • [25] Selective Cobalt over Nickel separation using neat and confined ionic liquids
    Boudesocque, Stephanie
    Viau, Lydie
    Dupont, Laurent
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2020, 8 (05):
  • [26] Application of ionic liquids to solvent extraction
    Kubota, Fukiko
    Goto, Masahiro
    SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2006, 13 : 23 - 36
  • [27] Feasibility of ionic liquids as alternative separation media for industrial solvent extraction processes
    Nakashima, K
    Kubota, F
    Maruyama, T
    Goto, M
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (12) : 4368 - 4372
  • [28] Cobalt(II)/nickel(II) separation from sulfate media by solvent extraction with an undiluted quaternary phosphonium ionic liquid
    Onghena, Bieke
    Valgaeren, Stijn
    Vander Hoogerstraete, Tom
    Binnemans, Koen
    RSC ADVANCES, 2017, 7 (57) : 35992 - 35999
  • [29] Separation of cobalt and nickel from chloride leach solution of nickel laterite ore by solvent extraction
    Liu, Yang
    Lee, Man Seung
    GEOSYSTEM ENGINEERING, 2016, 19 (05) : 214 - 221
  • [30] THE SOLVENT-EXTRACTION SEPARATION OF COBALT AND NICKEL USING SME-418
    DREISINGER, DB
    COOPER, WC
    CIM BULLETIN, 1982, 75 (842): : 118 - 118
12345