A mild copper catalyzed method for the selective deprotection of aryl allyl ethers

被引：8
|
作者：
Hemming, David S. [1 ]
Talbot, Eric P. [2 ]
Steel, Patrick G. [1 ]
机构：
[1] Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England
[2] GlaxoSmithKline Med Res Ctr, Gunnels Wood Rd, Stevenage SG1 2NY, Herts, England
来源：
TETRAHEDRON LETTERS | 2017年 / 58卷 / 01期
基金：
英国工程与自然科学研究理事会;
关键词：
Borylation; Deallylation; Bis(pinacolato)diboron; Copper; Protecting group; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; BORYL SUBSTITUTION; ALKYL-HALIDES; BETA-BORATION; ORGANIC HALIDES; EFFICIENT ROUTE; HYDROBORATION; DIBORON; CLEAVAGE; ESTERS;
D O I：
10.1016/j.tetlet.2016.11.084
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper boryl reagents enable the selective cleavage of aryl allyl ethers to the corresponding phenols in good to moderate yields. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：17 / 20
页数：4
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