Oxidation of 4-nitrotoluene by ozone in acetic anhydride in the presence of manganese sulfate

被引：2
|
作者：
Potapenko, EV [1 ]
Galstyan, GA [1 ]
Galstyan, AG [1 ]
Kudyukov, YP [1 ]
机构：
[1] E Ukrainian State Univ, Rubezhnoe Branch, Rubezhnoye, Lugansk Region, Ukraine
来源：
KINETICS AND CATALYSIS | 2001年 / 42卷 / 06期
关键词：
Manganese compounds - Ozonization - Sulfur compounds;
D O I：
10.1023/A:1013279115798
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction of 4-nitrotoluene oxidation with ozone in acetic anhydride in the presence of MnSO4 and sulfuric acid was studied. The main reaction product is 4-nitrobenzyl acetate, the yield of which is 63.2%. Based on an analysis of the experimental data, a mechanism of the catalytic ozonation of 4-nitrotoluene in acetic anhydride was proposed.
引用
收藏
页码：796 / 799
页数：4
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