Oxidation of 4-nitrotoluene by ozone in acetic anhydride in the presence of manganese sulfate

被引：2

作者：

Potapenko, EV ^{[1
]}

Galstyan, GA ^{[1
]}

Galstyan, AG ^{[1
]}

Kudyukov, YP ^{[1
]}

机构：

[1] E Ukrainian State Univ, Rubezhnoe Branch, Rubezhnoye, Lugansk Region, Ukraine

来源：

KINETICS AND CATALYSIS | 2001年 / 42卷 / 06期

关键词：

Manganese compounds - Ozonization - Sulfur compounds;

D O I：

10.1023/A:1013279115798

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of 4-nitrotoluene oxidation with ozone in acetic anhydride in the presence of MnSO4 and sulfuric acid was studied. The main reaction product is 4-nitrobenzyl acetate, the yield of which is 63.2%. Based on an analysis of the experimental data, a mechanism of the catalytic ozonation of 4-nitrotoluene in acetic anhydride was proposed.

引用

页码：796 / 799

页数：4

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