Ytterbium(III) triflate as a recyclable catalyst for the selective atom economic oxidation of benzyl alcohols to benzaldehydes

被引：0

作者：

Barrett, AGM ^{[1
]}

Braddock, DC

McKinnell, RM

Waller, FJ

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Air Prod & Chem Inc, Allentown, PA 18195 USA

来源：

SYNLETT | 1999年 / 09期

关键词：

alcohols; aldehydes; catalysis; lanthanides; oxidations;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ytterbium(III) triflate (10mol%) was found to catalyse the selective oxidation of a range of simple benzyl alcohols to benzaldehydes in good to excellent yield using a stoichiometric quantity of 69% nitric acid as the oxidant, and where the only by-products were water and oxides of nitrogen. The catalyst can be readily recovered and recycled by a simple evaporative process.

引用

页码：1489 / 1490

页数：2

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