Selective benzylic oxidation of alkylaromatics over Cu/SBA-15 catalysts under solvent-free conditions

被引：33

作者：

Neeli, Chinna Krishna Prasad ^{[1
]}

Narani, Anand ^{[1
]}

Marella, Ravi Kumar ^{[1
]}

Rao, Kamaraju Seetha Rama ^{[1
]}

Burri, David Raju ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Catalysis Lab, Hyderabad 500007, Andhra Pradesh, India

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 39卷

关键词：

Cu/SBA-15; Benzylic oxidation; Ethylbenzene; Acetophenone; TERT-BUTYL HYDROPEROXIDE; HYDROGEN-PEROXIDE; COMPLEXES; EFFICIENT; KETONES; BUTYLHYDROPEROXIDE; ETHYLBENZENE; HYDROCARBONS; CYCLOHEXANE; GLYCEROL;

D O I：

10.1016/j.catcom.2013.04.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

With the purpose of benzylic oxidation of alkylaromatics into corresponding ketones selectively under solvent-free conditions, cheap, simple and versatile Cu/SBA-15 catalyst system with the Cu loading of 5, 10, 15 and 20% has been prepared by impregnating SBA-15 support. Among Cu/SBA-15 catalysts, 10%Cu/SBA-15 exhibited superior activity and selectivity. (C) 2013 Elsevier B.V.. All rights reserved.

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页码：5 / 9

页数：5

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