Isolation and characterization of the first bis(2-pyridyl)-carbyltitanium(IV) complex derived from the C-O bond cleavage of the alkoxide ligand in CpTiMe2(OCMePy2).: X-ray crystal structure of [CpTi(μ-O)(CMePy2)]2 (Cp* = C5Me5)

被引：7

作者：

Fandos, R

Hernández, C

Otero, A

Rodríguez, A

Ruiz, MJ

Terreros, P

机构：

[1] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Ciencias Medio Ambiente, Toledo 45071, Spain

[2] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Quim, E-13071 Ciudad Real, Spain

[3] Univ Castilla La Mancha, ETS Ingn Ind, Dept Quim Inorgan Organ & Bioquim, E-13071 Ciudad Real, Spain

[4] CSIC, Inst Catalisis & Petr Quim, Madrid 28049, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b106481a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cp*TiMe2(OCMePy2) with one equivalent of xylylisocyanide (xylyl = 2,6-dimethylphenyl) affords the first bis(2-pyridyl)carbyl titanium(IV) as final complex in which the ligand acts as chelate and it is directly bonded to the titanium atom through both nitrogen atoms.

引用

页码：11 / 13

页数：3

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Isolation and characterization of the first bis(2-pyridyl)-carbyltitanium(IV) complex derived from the C-O bond cleavage of the alkoxide ligand in Cp*TiMe2(OCMePy2).: X-ray crystal structure of [Cp*Ti(μ-O)(CMePy2)]2 (Cp* = C5Me5)

Isolation and characterization of the first bis(2-pyridyl)-carbyltitanium(IV) complex derived from the C-O bond cleavage of the alkoxide ligand in CpTiMe2(OCMePy2).: X-ray crystal structure of [CpTi(μ-O)(CMePy2)]2 (Cp* = C5Me5)