Isolation and characterization of the first bis(2-pyridyl)-carbyltitanium(IV) complex derived from the C-O bond cleavage of the alkoxide ligand in CpTiMe2(OCMePy2).: X-ray crystal structure of [CpTi(μ-O)(CMePy2)]2 (Cp* = C5Me5)

被引：7

作者：

Fandos, R

Hernández, C

Otero, A

Rodríguez, A

Ruiz, MJ

Terreros, P

机构：

[1] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Ciencias Medio Ambiente, Toledo 45071, Spain

[2] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Quim, E-13071 Ciudad Real, Spain

[3] Univ Castilla La Mancha, ETS Ingn Ind, Dept Quim Inorgan Organ & Bioquim, E-13071 Ciudad Real, Spain

[4] CSIC, Inst Catalisis & Petr Quim, Madrid 28049, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b106481a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cp*TiMe2(OCMePy2) with one equivalent of xylylisocyanide (xylyl = 2,6-dimethylphenyl) affords the first bis(2-pyridyl)carbyl titanium(IV) as final complex in which the ligand acts as chelate and it is directly bonded to the titanium atom through both nitrogen atoms.

引用

页码：11 / 13

页数：3

共 50 条

[1] The new polynuclear titanium(IV) complex [(Cp*TiCl)(μ-O)2(Cp*Ti)2(μ-O)(μ-O)2]2Ti (Cp* is η5-C5Me5)
Chen, J
Hu, NH
Zhan, J
Li, YS
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : M337 - M338
[2] The synthesis of alkyl niobocene imido complexes and the X-ray crystal structure of [Nb(=O)CP2Me] (CP = η5-C5H5)
Antiñolo, A
López-Solera, I
Otero, A
Prashar, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 631 (1-2) : 151 - 156
[3] Synthesis and comparative X-ray diffraction study of first ruthenocene-based pincer palladium complexes, PdCl[{2,5-(But2PCH2)2C5H2}Ru(Cp′)] (Cp′ = C5H5 or C5Me5)
Kuklin, S. A.
Dolgushin, F. M.
Petrovskii, P. V.
Koridze, A. A.
RUSSIAN CHEMICAL BULLETIN, 2006, 55 (11) : 1950 - 1955
[4] Synthesis and comparative X-ray diffraction study of first ruthenocene-based pincer palladium complexes, PdCl[{2,5-(But2PCH2)2C5H2}Ru(Cp′)] (Cp′ = C5H5 or C5Me5)
S. A. Kuklin
F. M. Dolgushin
P. V. Petrovskii
A. A. Koridze
Russian Chemical Bulletin, 2006, 55 : 1950 - 1955
[5] Synthesis of 1,3-dimetallo-1,3-diphosphetane-2,4-diones. X-ray structure analysis of Cp*(CO)(2)FeP[Cr(CO)(5)]C(O)P[Fe(CO)(2)Cp*]C(O) (Cp*=eta(5)-C(5)Me(5))
Weber, L
Torwiehe, B
Bassmann, G
Stammler, HG
Neumann, B
ORGANOMETALLICS, 1996, 15 (01) : 128 - 132
[6] Synthesis of hydride tantalabenzocyclopentene and μ-alkylidene complexes by direct alkylation reactions of [TaCp*Cp′Cl2] -: NMR spectroscopic study and X-ray crystal structure of [TaCp*Cp′(H)(η2-CH2-CMe2-o-C6H4)], (Cp* = η5-C5Me5;: Cp′ = η5-C5H4SiMe3)
Castro, A
Galakhov, MV
Gómez, M
Gómez-Sal, P
Martín, A
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (06) : 1336 - 1342
[7] SYNTHESIS AND CRYSTAL-STRUCTURE OF SALTS WITH THE CATIONS [CP-STAR-2TI(H2O)2]2+ AND [CP-STAR-2TI(OH)(H2O)]+ (CP-STAR = ETA-5-(CH3)5C5)
THEWALT, U
HONOLD, B
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 348 (03) : 291 - 303
[8] The x-ray structure of [{Sn(η-C5Me5)} {Sn(η-C5Me5)(O3SCF3)2}]
de Lima, GM
Siebald, HGL
MAIN GROUP METAL CHEMISTRY, 2003, 26 (04): : 263 - 266
[9] (DIPHENYLPHOSPHINO)METHYL COMPLEXES OF TITANIUM AND ZIRCONIUM - SYNTHESIS AND CHARACTERIZATION - MOLECULAR-STRUCTURE OF CPCP-STAR-TI(CH2PPH2)2 (CP = C5H5, CP-STAR = C5ME5)
CUENCA, T
FLORES, JC
ROYO, P
LARSONNEUR, AM
CHOUKROUN, R
DAHAN, F
ORGANOMETALLICS, 1992, 11 (02) : 777 - 780
[10] Syntheses and reactivity of oxo niobocene complexes Cp2*Nb(=O)X (X = H, OCH3) and crystal structures of [Cp2*Nb(OH)F]BF4 and Cp2*Nb(=O)OC(O)H (Cp* = η5-C5Me5)
Brunner, H
Leblanc, JC
Lucas, D
Meier, W
Moise, C
Mugnier, Y
Nuber, B
Rigny, S
Sadorge, A
Wachter, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 566 (1-2) : 203 - 210

← 1 2 3 4 5 →

Isolation and characterization of the first bis(2-pyridyl)-carbyltitanium(IV) complex derived from the C-O bond cleavage of the alkoxide ligand in Cp*TiMe2(OCMePy2).: X-ray crystal structure of [Cp*Ti(μ-O)(CMePy2)]2 (Cp* = C5Me5)

Isolation and characterization of the first bis(2-pyridyl)-carbyltitanium(IV) complex derived from the C-O bond cleavage of the alkoxide ligand in CpTiMe2(OCMePy2).: X-ray crystal structure of [CpTi(μ-O)(CMePy2)]2 (Cp* = C5Me5)