Synthesis, Surface Active and Thermodynamic Parameters of Novel Quaternary Ammonium Salts

被引：13
|
作者：
Asadov, Ziyafaddin H. [1 ]
Rahimov, Ravan A. [1 ]
Ahmadova, Gulnara A. [1 ]
Mammadova, Khuraman A. [1 ]
机构：
[1] Azerbaijan Natl Acad Sci, Inst Petrochem Proc, Baku 1025, Azerbaijan
来源：
JOURNAL OF SURFACTANTS AND DETERGENTS | 2012年 / 15卷 / 06期
关键词：
Cationic surfactant; Micellization; Adsorption; Oil spill; ANTIMICROBIAL ACTIVITIES; CATIONIC SURFACTANTS; EPICHLOROHYDRIN;
D O I：
10.1007/s11743-012-1385-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Reactions of octanol, nonanol, decanol, and dodecanol with epichlorohydrin were carried out in the presence of sodium hydroxide as a catalyst. The synthesized non-ionic surfactants were modified with triethanolamine. Surface activity at the water-air interface and electrical conductivity of the resulting surfactants at 10, 20, 30 and 40 A degrees C were determined and thermodynamic parameters of micellization and adsorption were calculated. It was established that the synthesized quaternary ammonium salts have the ability to localize thin crude oil films on the water surface formed due to spill.
引用
收藏
页码：721 / 727
页数：7
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