Molecularly Imprinted Polymers Based Electrochemical Sensor for 2,4-Dichlorophenol Determination

被引:19
|
作者
Liu, Benzhi [1 ]
Cang, Hui [1 ]
Jin, Jianxiang [1 ]
机构
[1] Yancheng Inst Technol, Sch Environm Sci & Engn, Yancheng 224051, Peoples R China
基金
中国国家自然科学基金;
关键词
2,4-dichlorophenol; electrochemical sensor; molecularly imprinted polymers; DOPAMINE RECOGNITION; CARBON NANOTUBES; BIOSENSOR; MEMBRANE; ACID; CHLOROPHENOLS; NANOPARTICLES;
D O I
10.3390/polym8080309
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A molecularly imprinted polymers based electrochemical sensor was fabricated by electropolymerizing pyrrole on a Fe3O4 nanoparticle modified glassy carbon electrode. The sensor showed highly catalytic ability for the oxidation of 2,4-dichlorophenol (2,4-DCP). Square wave voltammetry was used for the determination of 2,4-DCP. The oxidation peak currents were proportional to the concentrations of 2,4-DCP in the range of 0.04 to 2.0 mu M, with a detection limit of 0.01 mu M. The proposed sensor was successfully applied for the determination of 2,4-DCP in water samples giving satisfactory recoveries.
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页数:9
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