5,15-diaminotetrabenzoporphyrins: Synthesis and spectral properties

被引：3
|
作者：
Yakubov, L. A. [1 ]
Galanin, N. E. [1 ]
Shaposhnikov, G. P. [1 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo 153000, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2012年 / 82卷 / 03期
关键词：
SUBSTITUTED TETRABENZOPORPHYRINS;
D O I：
10.1134/S1070363212030206
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A zinc complex of 5,15-di(N-phthalimidyl)tetrabenzoporphyrin was obtained by the reaction of Ncarboxymethylphthalimide with 1-oxo-1H-3-(1-oxoisoindolin-3-ylidenemethyl)isoindole and zinc oxide. The complex demetallation affords 5,15-di(N-phthalimidyl)tetrabenzoporphyrin. The reaction of N-phthalimidylsubstituted tetrabenzoporphyrins with hydrazine hydrate leads to the formation of 5,15-diaminotetrabenzoporphyrins. Spectral properties of these compounds were studied.
引用
收藏
页码：482 / 487
页数：6
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