2,5-bis(di-tert-butylhydroxysilyl)furan as a host molecule for potassium fluoride, H2O, NH3 and MeNH2

被引：0

作者：

Klingebiel, U ^{[1
]}

Neugebauer, P ^{[1
]}

Müller, I ^{[1
]}

Noltemeyer, M ^{[1
]}

Usón, I ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 03期

关键词：

silicon; furan; host-guest complexes; structure elucidation;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,5-Bis(di-tert-butylfluorosilyl)furan reacts with potassium hydroxide in a 1:2 molar ratio to give 2,5-bis(di-tert-butylhydroxysilyl)furan, O(CRCH)(2) [R = SiOH(CMe3)(2) (1)], Compound I is very selective in its adduct formation and forms host-guest complexes in the presence of KF [1.1/2KF (2)], H2O [1.H2O (3)], NH3 [MeNH3 (4)] and MeNH2 [1.2MeNH(2) (5)], The host-guest complexes are stable at room temperature. Compound 4 is the first neutral ammonia cage that is stable up to 100 degreesC. The crystal structures of 2, 3, 4 and 5 have been determined.

引用

页码：717 / 722

页数：6

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