2,5-bis(di-tert-butylhydroxysilyl)furan as a host molecule for potassium fluoride, H2O, NH3 and MeNH2

被引：0

作者：

Klingebiel, U ^{[1
]}

Neugebauer, P ^{[1
]}

Müller, I ^{[1
]}

Noltemeyer, M ^{[1
]}

Usón, I ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 03期

关键词：

silicon; furan; host-guest complexes; structure elucidation;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,5-Bis(di-tert-butylfluorosilyl)furan reacts with potassium hydroxide in a 1:2 molar ratio to give 2,5-bis(di-tert-butylhydroxysilyl)furan, O(CRCH)(2) [R = SiOH(CMe3)(2) (1)], Compound I is very selective in its adduct formation and forms host-guest complexes in the presence of KF [1.1/2KF (2)], H2O [1.H2O (3)], NH3 [MeNH3 (4)] and MeNH2 [1.2MeNH(2) (5)], The host-guest complexes are stable at room temperature. Compound 4 is the first neutral ammonia cage that is stable up to 100 degreesC. The crystal structures of 2, 3, 4 and 5 have been determined.

引用

页码：717 / 722

页数：6

共 50 条

[1] Vapor-liquid equilibria of NH3 in (NH3+ H2O) and (NH3 + PZ + H2O) system
Liu, Jinzhao
Wang, Shujuan
Hartono, Ardi
Svendsen, Hallvard F.
Kim, Inna
Chen, Changhe
FLUID PHASE EQUILIBRIA, 2011, 311 : 30 - 35
[2] Solubility of ammonium paratungstate in the system NH3·H2O·H2O
WAN Linsheng
RareMetals, 2003, (01) : 10 - 13
[3] REACTION OF NO+ AND NO+.(H2O)N WITH H2O AND NH3
FEHSENFE.FC
FERGUSON, EE
BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1971, 16 (02): : 213 - &
[4] Comment: Complexes of CH2NH2+ with NH3 and H2O
Uggerud, E
EUROPEAN MASS SPECTROMETRY, 1996, 2 (2-3): : 193 - 195
[5] A Study of Solid CO2/NH3 and NH3/H2O by XPS
Dillingham, T.R.
Cornelison, D.M.
Surface Science Spectra, 2002, 9 (01): : 12 - 20
[6] ON THE REACTIONS OF F ATOMS WITH H2O, H2O2, AND NH3
WALTHER, CD
WAGNER, HG
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1983, 87 (05): : 403 - 409
[7] Theoretical study of formation of ion pairs in (NH3·HCl)(H2O)6 and (NH3·HF)(H2O)6
Roger L. DeKock
Benjamin M. Brandsen
John R. Strikwerda
Theoretical Chemistry Accounts, 2011, 130 : 871 - 881
[8] Theoretical study of formation of ion pairs in (NH3•HCl)(H2O)6 and (NH3•HF)(H2O)6
DeKock, Roger L.
Brandsen, Benjamin M.
Strikwerda, John R.
THEORETICAL CHEMISTRY ACCOUNTS, 2011, 130 (4-6) : 871 - 881
[9] (NH3)2（H2O）2团簇结构探究
杨华
赵飞
周鹏
王全军
张艳娥
胡维军
西华大学学报(自然科学版), 2008, (05) : 63 - 67+78+109
[10] VOLUME PROFILES AS MECHANISTIC INFORMATION FOR AQUATIONS OF CIS-COCL-(NH3)4(H2O)2+, CIS-COBR-(NH3)4(H2O)2+, CIS-CONO3-(NH3)4(H2O)2+
KITAMURA, Y
ITOH, T
TAKEUCHI, M
INORGANIC CHEMISTRY, 1986, 25 (22) : 3887 - 3890

← 1 2 3 4 5 →