A detailed study of isothermal crystallization of As2Se3 undercooled liquid

被引：7

作者：

Holubova, Jana ^{[1
]}

Cernosek, Zdenek ^{[1
]}

Cernoskova, Eva ^{[2
,3
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice, Czech Republic

[2] Czech Acad Sci, Inst Macromol Chem, Joint Lab Solid State Chem, Vvi, Pardubice, Czech Republic

[3] Univ Pardubice, Pardubice, Czech Republic

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 114卷 / 03期

关键词：

Nucleation; Crystallization; As2Se3; Differential scanning calorimetry; HOMOGENEOUS CRYSTAL NUCLEATION; STRUCTURAL RELAXATION; SILICATE-GLASSES; KINETICS; GROWTH;

D O I：

10.1007/s10973-013-3110-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Isothermal crystallization of an As2Se3 undercooled melt was studied by differential scanning calorimetry and described using the classical theory of nucleation and crystal growth. The maximum rate of nucleation and crystal growth was observed to occur at approximately 235 and 350 A degrees C, respectively. The activation energies of nucleation and crystal growth were determined to be Delta E (D) = 311 kJ mol(-1) and Delta E* = 104 kJ mol(-1), respectively. The temperature dependencies of both the activation free energy of nucleation, Delta G*, and the critical diameter, r*, were also calculated.

引用

页码：997 / 1002

页数：6

共 50 条

[41] Neutron scattering study of As2Se3 glass fibres
Physics and Chemistry of Glasses, 1997, 38 (05):
[42] A neutron scattering study of As2Se3 glass fibres
King, WA
Clare, AG
LaCourse, WC
Volin, K
Wright, AC
Wanless, AJ
PHYSICS AND CHEMISTRY OF GLASSES, 1997, 38 (05): : 269 - 276
[43] Au/As2Se3/Ag/As2Se3/Yb Schottky Barriers Designed as Multifunctional Devices
Al Harbi, S. R.
Qasrawi, A. F.
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2020, 67 (03) : 1305 - 1309
[44] AS2SE3(SB2SE3)-COSE SYSTEM
ALLAZOV, MR
MOVSUMZADE, AA
SHIRINOV, SM
ALIEVA, IF
ZHURNAL NEORGANICHESKOI KHIMII, 1984, 29 (12): : 3122 - 3127
[45] STRUCTURE OF LIQUID AS2SE3 AND GESE2 BY NEUTRON-DIFFRACTION
UEMURA, O
SATOW, T
MUNO, D
SAGARA, Y
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1978, 30 (02) : 155 - 162
[46] EXAFS MEASUREMENTS FOR LIQUID AS2SE3 AT HIGH-TEMPERATURES AND PRESSURES
TAMURA, K
HOSOKAWA, S
INUI, M
YAO, M
ENDO, H
HOSHINO, H
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 150 (1-3) : 351 - 355
[47] Local structures in glassy and liquid As2Se3 -: an anomalous X-ray scattering study
Hosokawa, S
Kawakita, Y
Pilgrim, WC
Hensel, F
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 293 : 153 - 157
[48] Structural evolution mechanisms of amorphous and liquid As2Se3 at high pressures
Properzi, L.
Santoro, M.
Minicucci, M.
Iesari, F.
Ciambezi, M.
Nataf, L.
Le Godec, Y.
Irifune, T.
Baudelet, F.
Di Cicco, A.
PHYSICAL REVIEW B, 2016, 93 (21)
[49] Photosensitivity of In2Se3/As2Se3 barrier structures
Andriesh, AM
Iovu, MS
Khanchevskaya, EG
PISMA V ZHURNAL TEKHNICHESKOI FIZIKI, 1995, 21 (14): : 88 - 91
[50] Influence of holmium impurities on photoelectric properties of As2Se3 and (As2S3)0.3(As2Se3)0.7
I. I. Burdiyan
E. A. Senokosov
V. V. Kosyuk
R. A. Pynzar’
Semiconductors, 2006, 40 : 1218 - 1221

← 1 2 3 4 5 →