First Tribo-Excited Chemical Reaction of a Stacked Lanthanide Coordination Polymer with an in Situ Reaction Monitor

被引：11

作者：

Kitagawa, Yuichi ^{[1
,2
]}

Naito, Ayu ^{[3
]}

Fushimi, Koji ^{[1
]}

Hasegawa, Yasuchika ^{[1
,2
]}

机构：

[1] Hokkaido Univ, Fac Engn, Kita Ku, Kita 13 Nishi 8, Sapporo, Hokkaido 0608628, Japan

[2] Hokkaido Univ, Inst Chem React Design & Discovery WPI ICReDD, Kita Ku, Kita 21 Nishi 10, Sapporo, Hokkaido 0010021, Japan

[3] Hokkaido Univ, Grad Sch Chem Sci & Engn, Kita Ku, Kita 13 Nishi 8, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2021年 / 27卷 / 07期

关键词：

energy transfer; luminescence; photophysics; UV; Vis spectroscopy; TRIBOLUMINESCENCE; PHOTOCHEMISTRY; PHOTOOXIDATION; ANTHRACENE;

D O I：

10.1002/chem.202004485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tribo-excited chemical reaction using a stacked lanthanide coordination polymer is demonstrated for the first time. The polymer is composed of a Eu-III ion, hexafluoroacetylacetonato ligands, and an anthracene-based phosphine oxide bridge. The tightly stacked structure with hydrogen bonding was characterized by X-ray crystal structure analysis. The mechanical stimulus leads to tribo-excited oxidation in the Eu-III coordination polymer. Electron ionization mass spectroscopy and photo-spectroscopic analysis reveal that the chemical product afforded by tribo-oxidation is different from that obtained by photo-oxidation.

引用

页码：2279 / 2283

页数：5

共 31 条

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Kitagawa, Yuichi
Naito, Ayu
Aikawa, Kota
Shima, Kaori
Shoji, Sunao
Fushimi, Koji
Hasegawa, Yasuchika
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (16)
[2] Four unexpected lanthanide coordination polymers involving in situ reaction of solvent N, N-Dimethylformamide
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Tong, Wen-Quan
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Chang, Wen-Gui
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JOURNAL OF SOLID STATE CHEMISTRY, 2015, 225 : 216 - 221
[3] In situ facile nitration in hydrothermal reaction generating novel metal-organic coordination polymer
Xiao, Hong-Ping
Zhu, Long-Guan
INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (11) : 1125 - 1128
[4] Synthesis, Structure and Catalytic Properties of Mn(II) Coordination Polymer through in Situ Ligand Reaction
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CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2021, 37 (04) : 751 - 757
[5] Optimizing hydrothermal reaction conditions for lanthanide coordination polymer formation: A study of the 1,4-benzenedicarboxylate system
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de Lill, Daniel
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[6] Interfacial rheology for probing the in-situ chemical reaction at interfaces of molten polymer systems
El Omari, Y.
Yousfi, M.
Duchet-Rumeau, J.
Maazouz, A.
MATERIALS TODAY COMMUNICATIONS, 2023, 35
[7] Chemical reaction-inspired crystal growth of a coordination polymer toward morphology design and control
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Tanaka, Daisuke
Kitahata, Hiroyuki
Araki, Sumiko
Matsuda, Ryotaro
Yoshikawa, Kenichi
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Takata, Masaki
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Journal of the American Chemical Society, 2006, 128 (49): : 15799 - 15808
[8] Chemical reaction-inspired crystal growth of a coordination polymer toward morphology design and control
Masaoka, Shigeyuki
Tanaka, Daisuke
Kitahata, Hiroyuki
Araki, Sumiko
Matsuda, Ryotaro
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) : 15799 - 15808
[9] Synthesis, Characterization and Photoluminescent Property of a Trinucleated Cadmium (II) Coordination Polymer Involving In Situ Ligand Reaction
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Dinesh K. Gupta
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Journal of Chemical Crystallography, 2013, 43 : 82 - 90
[10] Synthesis, Characterization and Photoluminescent Property of a Trinucleated Cadmium (II) Coordination Polymer Involving In Situ Ligand Reaction
Singh, Sadhana
Gupta, Dinesh K.
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JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2013, 43 (02) : 82 - 90

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