Synthesis, Characterization and Crystal Structure of a Novel Mn(II) Coordination Polymer Material with Rigid Tetracarboxylate and Chelating N-Donor Co-Ligand

被引：5
|
作者：
Liu, Yaru [1 ]
Pan, Yutian [2 ]
机构：
[1] N Univ China, Sch Sci, Taiyuan 030051, Shanxi, Peoples R China
[2] N Univ China, Sch Mech Engn, Taiyuan 030051, Shanxi, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 10期
关键词：
coordination polymer; crystal structure; Mn Complex; porous framework; ARCHITECTURES; 3D;
D O I：
10.1080/15533170903433204
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new metal-organic framework, [Mn(DDA)0.5(phen)(H2O)2 center dot 2H2O]n (1) (H4DDA = 4,4' -diazenediyldiphthalic acid and phen = 1,10-phenanthroline) have been syntheiszed through hydrogen methods and characterized by IR and single-crystal X-ray diffraction. It crystallizes in triclinic, space group p-1 with a = 9.432(11) angstrom, b = 10.697(12) angstrom, c = 10.751(12) angstrom, = 87.95(2)degrees, = 67.76(1)degrees, = 76.08(2)degrees, Z = 2. The complex exhibits interesting 1D chain structure containing dinuclear Mn subunits, which is further extended into 2D supramolecuar double chain framework via - interactions.
引用
收藏
页码：685 / 689
页数：5
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