Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes

被引：65
|
作者：
Aouf, Chahinez [1 ]
Thiery, Emilie [1 ]
Le Bras, Jean [1 ]
Muzart, Jacques [1 ]
机构：
[1] Univ Reims, Inst Chim Mol Reims, CNRS, UMR 6229,UFR Sci Exactes & Nat, F-51687 Reims 2, France
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 18期
关键词：
C-H ALKENYLATION; FREE NH-INDOLES; BOND FUNCTIONALIZATION; MOLECULAR-OXYGEN; OLEFINS; ARENES; ACTIVATION; OXIDANT; C3-ALKENYLATION; THIOPHENES;
D O I：
10.1021/ol901570p
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.
引用
收藏
页码：4096 / 4099
页数：4
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