Construction and photoluminescence properties of two novel zinc(II) and cadmium(II) benzyl-tetrazole coordination polymers

被引：41
|
作者：
Liu, Biao [1 ]
Qiu, Yong-Cai [1 ]
Peng, Guo [1 ]
Ma, Li [1 ]
Jin, Li-Ming [1 ]
Cai, Jin-Biao [1 ]
Deng, Hong [1 ]
机构：
[1] S China Normal Univ, Power Generat Guangdong Univ, Key Lab Electrochem Technol Energy Storage, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Tetrazole; Helical chain; Fluorescence; Lifetime; LIGAND SYNTHESIS; 5-SUBSTITUTED; 1H-TETRAZOLES; SUPRAMOLECULAR ARCHITECTURES; COPPER(II); WATER; DIFFRACTION; FRAMEWORK; NITRILES; BROMIDE; EPR;
D O I：
10.1016/j.inoche.2009.09.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new d(10) coordination polymers. Zn(Beta)(2) (1) and Cd-2(Beta)(3)Cl(H2O) (2) (Hbeta = 5-benzyl-tetrazole) have been synthesized by the in situ [3 + 2] cycloaddition reaction of 5-benzylacetonitrile, sodium azide and MCl2 [M = Zn (1); M = Cd (2)] under hydrothermal condition, Complex 1 is a coordination polymer comprised of numerous mildly undulated two-dimensional (2D) layers with a (4,4) topological network; while complex 2 is a 3D coordination framework constructed from the interconnection of various helical chains through cadmium-chlorine bridges. Furthermore, the luminescence properties of two complexes have been investigated. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：1200 / 1203
页数：4
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