RhIII-Catalyzed C-H Olefination of Benzoic Acids under Mild Conditions using Oxygen as the Sole Oxidant

被引：53

作者：

Jiang, Quandi ^{[1
]}

Zhu, Changlei ^{[1
]}

Zhao, Huaiqing ^{[1
]}

Su, Weiping ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 03期

关键词：

C-H activation; dioxygen; Heck reaction; Michael addition; rhodium; N BOND FORMATION; CARBOXYLIC-ACIDS; ORGANIC-CHEMICALS; MOLECULAR-OXYGEN; OXIDATION; METAL; ACTIVATION; INDOLES; ARENES; FUNCTIONALIZATION;

D O I：

10.1002/asia.201500601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phthalide skeletons have been synthesized for the first time through a Rh-III-catalyzed C-H olefination of benzoic acids under mild conditions using oxygen as the sole oxidant. Aromatic acids bearing a variety of functional groups could react with diverse alkenes to afford the desired cyclized lactones or uncyclized alkenylarenes in moderate-to-excellent yields.

引用

页码：356 / 359

页数：4

共 50 条

[21] Palladium-Catalyzed Olefination and Arylation of Polyfluoroarenes Using Molecular Oxygen as the Sole Oxidant
Huang, Qiufeng
Zhang, Xinyu
Qiu, Lin
Wu, Jiajun
Xiao, Hanbing
Zhang, Xiaofeng
Lin, Shen
ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (16-17) : 3753 - 3757
[22] RhIII-Catalyzed C-H Activation: A Versatile Route towards Various Polycyclic Pyridinium Salts
Luo, Ching-Zong
Gandeepan, Parthasarathy
Jayakumar, Jayachandran
Parthasarathy, Kanniyappan
Chang, Yu-Wei
Cheng, Chien-Hong
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (42) : 14181 - 14186
[23] Water as a Hydroxy Source in a RhIII-Catalyzed Directed C-H Hydroxylation of 2-Arylpyridines
Kim, Kiseong
Hyun, Jaeyong
Kim, Jin
Kim, Hyunwoo
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 6 (07) : 907 - 912
[24] Palladium Catalyzed C-H Olefination of Indolizines at the 1-Position with Molecular Oxygen as the Terminal Oxidant
Lu, Mingzhu
Shi, Fei
Ji, Meishan
Kan, Yuhe
Hu, Huayou
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 8 (08) : 1555 - 1560
[25] RhIII-Catalyzed C-H (Het)arylation/Vinylation of N-2,6-Difluoroaryl Acrylamides
Wang, Huai-Wei
Qiao, Yu-Han
Wu, Jia-Xue
Wang, Qiu-Ping
Tian, Meng-Xin
Li, Yong-Fei
Yao, Qing-Xia
Li, Da-Cheng
Dou, Jian-Min
Lu, Yi
ORGANIC LETTERS, 2021, 23 (03) : 656 - 662
[26] Cp*RhIII-Catalyzed Sulfonamide-Directed Ortho Arene C-H Carbenoid Functionalization with Pyridotriazoles
Dong, Yi
Chen, Jiajing
Cui, Yunjian
Bao, Liangliang
Xu, Heng
ORGANIC LETTERS, 2020, 22 (03) : 772 - 775
[27] RhIII-Catalyzed C-H Activation of Aryl Hydroxamates for the Synthesis of Isoindolinones (vol 26, 10729, 2020)
Shaaban, Saad
Davies, Caitlin
Merten, Christian
Flegel, Jana
Otte, Felix
Strohmann, Carsten
Waldmann, Herbert
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (65) : 15046 - 15046
[28] RhIII-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection
Kim, Ju Hyun
Gensch, Tobias
Zhao, Dongbing
Stegemann, Linda
Strassert, Cristian A.
Glorius, Frank
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (37) : 10975 - 10979
[29] Palladium-Catalyzed C-H Direct Arylation of Uracils and Caffeines with Arenes Using Molecular Oxygen as the Sole Oxidant
Pan, Guoshuai
Wu, Kongchuan
Deng, Zeying
Zhang, Xinyu
Zhang, Xiaofeng
Lin, Shen
Huang, Qiufeng
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2018, 38 (08) : 2076 - 2084
[30] Ruthenium catalyzed C-H activation and decarboxylation under mild conditions
Zhao, Pinjing
Zhang, Ting
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247

← 1 2 3 4 5 →