RhIII-Catalyzed C-H Olefination of Benzoic Acids under Mild Conditions using Oxygen as the Sole Oxidant

被引：53

作者：

Jiang, Quandi ^{[1
]}

Zhu, Changlei ^{[1
]}

Zhao, Huaiqing ^{[1
]}

Su, Weiping ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 03期

关键词：

C-H activation; dioxygen; Heck reaction; Michael addition; rhodium; N BOND FORMATION; CARBOXYLIC-ACIDS; ORGANIC-CHEMICALS; MOLECULAR-OXYGEN; OXIDATION; METAL; ACTIVATION; INDOLES; ARENES; FUNCTIONALIZATION;

D O I：

10.1002/asia.201500601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phthalide skeletons have been synthesized for the first time through a Rh-III-catalyzed C-H olefination of benzoic acids under mild conditions using oxygen as the sole oxidant. Aromatic acids bearing a variety of functional groups could react with diverse alkenes to afford the desired cyclized lactones or uncyclized alkenylarenes in moderate-to-excellent yields.

引用

页码：356 / 359

页数：4

共 50 条

[1] Palladium-catalyzed C-H olefination of uracils and caffeines using molecular oxygen as the sole oxidant
Zhang, Xinyu
Su, Lv
Qiu, Lin
Fan, Zhenwei
Zhang, Xiaofeng
Lin, Shen
Huang, Qiufeng
ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 15 (16) : 3499 - 3506
[2] Cp*RhIII-Catalyzed C-H Amidation of Ferrocenes
Wang, Shao-Bo
Gu, Qing
You, Shu-Li
ORGANOMETALLICS, 2017, 36 (22) : 4359 - 4362
[3] RhIII-Catalyzed C-H Activation of Aryl Hydroxamates for the Synthesis of Isoindolinones
Shaaban, Saad
Davies, Caitlin
Merten, Christian
Flegel, Jana
Otte, Felix
Strohmann, Carsten
Waldmann, Herbert
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (47) : 10729 - 10734
[4] Urea-Substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated RhIII-Catalyzed ortho-C-H Olefination of Benzoic Acid Derivatives
Maurer, David
Breit, Bernhard
CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (08) : 2643 - 2648
[5] Rh(III)-catalyzed C-H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
Lu, Yi
Wang, Huai-Wei
Spangler, Jillian E.
Chen, Kai
Cui, Pei-Pei
Zhao, Yue
Sun, Wei-Yin
Yu, Jin-Quan
CHEMICAL SCIENCE, 2015, 6 (03) : 1923 - 1927
[6] RhIII-Catalyzed Hydroarylation of Internal Alkynes through C-H Bond Activation
Wang, Cheng-Qiang
Feng, Chao
Loh, Teck-Peng
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 5 (08) : 1002 - 1007
[7] RhIII-Catalyzed Directed C-H Bromination and Iodination to Synthesize Atropisomeric Biaryls
Kim, Kiseong
Hyun, Jaeyong
Kim, Jin
Kim, Hyunwoo
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 5 (09) : 1107 - 1110
[8] Enaminones as Synthons for a Directed C-H Functionalization: RhIII-Catalyzed Synthesis of Naphthalenes
Zhou, Shuguang
Wang, Jinhu
Wang, Lili
Song, Chao
Chen, Kehao
Zhu, Jin
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (32) : 9384 - 9388
[9] A Unique Alkylation of Azobenzenes with Allyl Acetates by RhIII-Catalyzed C-H Functionalization
Deng, Hong
Li, Hongji
Wang, Lei
ORGANIC LETTERS, 2015, 17 (10) : 2450 - 2453
[10] 2-Pyridyl Sulfoxide Directed Pd(II)-Catalyzed C-H Olefination of Arenes with Molecular Oxygen as the Sole Oxidant
Yadav, Mamta
Jat, Ram Singh
Sarma, Bibek
Bhanuchandra, M.
SYNTHESIS-STUTTGART, 2021, 53 (13): : 2269 - 2276

← 1 2 3 4 5 →