trans-Diaquabis(2-pyridylethanol-N,O)cobalt(II) disaccharinate

被引：6
|
作者：
Yilmaz, VT [1 ]
Hamamci, S
Thöne, C
机构：
[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Turkey
[2] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S1600536802020081
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [ Co( pyet)(2)( H2O)(2)]( sac)(2) ( sac(-) is the saccharinate anion, C7H4NO3S-, and pyet is 2- pyridylethanol, C7H9NO) contains sac(-) ions and [ Co( H2O)(2)( pyet)(2)](2+) cations, in which the Co2+ ion lies on a centre of symmetry and is octahedrally coordinated by two water and two neutral pyet molecules, which act as N- and O- donor bidentate ligands forming two symmetrically- related six- membered chelate rings. The crystal packing is determined by hydrogen bonding, as well as weak sac(-) -sac(-) pi - pi- stacking interactions, resulting in a three- dimensional network.
引用
收藏
页码：M702 / M704
页数：3
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