Dynamics of sheared droplets filled with non-Brownian particles

被引:2
|
作者
Van Ammel, Helene [1 ]
Moldenaers, Paula [1 ]
Cardinaels, Ruth [1 ,2 ]
机构
[1] Katholieke Univ Leuven, Dept Chem Engn, Soft Matter Rheol & Technol, Box 2424,Celestijnenlaan 200F, BE-3001 Leuven, Belgium
[2] TU Eindhoven, Dept Mech Engn, Polymer Technol, Box 513, NL-5600 MB Eindhoven, Netherlands
关键词
Emulsions; Polymer blends; Particle-filled systems; Non-Brownian particles; Droplet dynamics; IMMISCIBLE POLYMER BLENDS; MODIFIED LAYERED SILICATE; PA6 DISPERSED PHASE; BREAK-UP; SELECTIVE LOCALIZATION; MECHANICAL-PROPERTIES; MORPHOLOGY EVOLUTION; CARBON NANOTUBES; SINGLE DROPLETS; PP/PA6; BLENDS;
D O I
10.1007/s00397-020-01240-6
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
The dynamics of single droplets containing non-Brownian particles are studied. The particle over droplet size ratio (r/R) is changed by using different particle sizes (r/R = 0.02-0.4). Additionally, the effect of particle concentration (5-20 vol%) is investigated. The dynamics of droplets with r/R = 0.02 show good agreement with the corresponding particle-free reference system which has a comparable viscosity ratio. Hence, this droplet phase can be considered as a homogenous medium characterized by its bulk viscosity which is governed by the particle concentration. However, droplets with r/R >= 0.1 show a more suppressed deformation and slower transient dynamics and, therefore, behave as a slightly more viscous medium than expected based on their bulk viscosity. These effects become more pronounced at higher particle concentrations and higher r/R. Moreover, local particle effects like asymmetric droplet shapes, oscillating droplet shapes, and tip streaming start to influence the droplet dynamics at particle concentrations around 15 vol%.
引用
收藏
页码:935 / 949
页数:15
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