Properties of Mn-doped FINEMET

被引:26
|
作者
Brzozowski, R. [1 ]
Wasiak, M. [4 ]
Piekarski, H. [4 ]
Sovak, P. [2 ]
Uznanski, P. [3 ]
Moneta, M. E. [1 ]
机构
[1] Univ Lodz, Katedra Fizyki Ciala Stalego, PL-90236 Lodz, Poland
[2] Univ PJ Safarika Kosiciach, Prirod Fak, Kosice 04101, Slovakia
[3] Ctr Badan Mol & Makromol PAN, PL-90363 Lodz, Poland
[4] Univ Lodz, Katedra Chem Fizycznej, PL-90236 Lodz, Poland
关键词
FINEMET; Mn doping; DSC; XRD; Mossbauer spectroscopy; MAGNETIC-PROPERTIES; NANOCRYSTALLIZATION; CRYSTALLIZATION; BEHAVIOR; HYPERFINE; NIOBIUM;
D O I
10.1016/j.jallcom.2008.02.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural, thermodynamical and magnetic properties of Fe73.5-xSi13.5B9Cu1Nb3Mnx amorphous alloys, with Mn content x = 1, 3-15, were studied by means of X-ray diffraction (XRD), differential scanning calorimetry (DSC), Mossbauer spectroscopy (MS) and energy-dispersive X-rays (EDX), as-quenched and after annealing. The alloys with x <= 7 suffer primary (above similar to 550 degrees C) and secondary (below similar to 680 degrees C) crystallisation, whereas the alloys with x >= 9 only at similar to 580 degrees C. Mn doping results in increase (for x <= 7) and then (for x >= 9) in decrease of grain size. The hyperfine field of the amorphous precursor and remainder substantially decrease with increase of Mn content x, whereas the fields in crystallites remain nearly independent of x. A paramagnetic component appears at x similar to 9 and grows with x. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:5 / 11
页数:7
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