Metal-organic frameworks as catalysts: the role of metal active sites

被引：276

作者：

Valvekens, Pieterjan ^{[1
]}

Vermoortele, Frederik ^{[1
]}

De Vos, Dirk ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 06期

关键词：

MOLECULAR-SIEVES; MESOPOROUS ORGANOSILICAS; HETEROGENEOUS CATALYSIS; OXIDATION; MOFS; CONVERSION; VANADIUM; COMBINATION; COMPLEXES; FTIR;

D O I：

10.1039/c3cy20813c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this perspective we first critically compare the use of metal-organic frameworks (MOFs) as supports for catalytic functions with the possibilities offered by other classes of porous materials. We then discuss the incidental or deliberate formation of active sites in MOF lattices, and review some strategies to control the number and activity of these sites, ultimately resulting in MOF catalysts with improved performance.

引用

页码：1435 / 1445

页数：11

共 50 条

[41] Metal-organic frameworks
James, SL
CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) : 276 - 288
[42] Metal-organic frameworks
Birkett, Jim
CHEMICAL & ENGINEERING NEWS, 2017, 95 (30) : 2 - 2
[43] The Role of Metal-Organic Frameworks in Electronic Sensors
Zhang, Lin-Tao
Zhou, Ye
Han, Su-Ting
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (28) : 15192 - 15212
[44] Metal-Organic Framework-Based Catalysts with Single Metal Sites
Wei, Yong-Sheng
Zhang, Mei
Zou, Ruqiang
Xu, Qiang
CHEMICAL REVIEWS, 2020, 120 (21) : 12089 - 12174
[45] Design of Multivariate Biological Metal-Organic Frameworks: Toward Mimicking Active Sites of Enzymes
Navarro-Alapont, Javier
Negro, Cristina
Navalon, Sergio
Dhakshinamoorthy, Amarajothi
Armentano, Donatella
Ferrando-Soria, Jesus
Pardo, Emilio
INORGANIC CHEMISTRY, 2024, 63 (29) : 13681 - 13688
[46] Electrochemical Instability of Metal-Organic Frameworks: In Situ Spectroelectrochemical Investigation of the Real Active Sites
Zheng, Weiran
Liu, Mengjie
Lee, Lawrence Yoon Suk
ACS CATALYSIS, 2020, 10 (01): : 81 - +
[47] Creating Dual Active Sites in Conductive Metal-Organic Frameworks for Efficient Water Splitting
He, Yuqian
Yan, Feng
Zhang, Xiao
Zhu, Chunling
Zhao, Yingying
Geng, Bo
Chou, Shulei
Xie, Ying
Chen, Yujin
ADVANCED ENERGY MATERIALS, 2023, 13 (20)
[48] Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis
Song, Feijie
Zhang, Teng
Wang, Cheng
Lin, Wenbin
PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2012, 468 (2143): : 2035 - 2052
[49] Amino-based metal-organic frameworks as stable, highly active basic catalysts
Gascon, Jorge
Aktay, Ugur
Hernandez-Alonso, Maria D.
van Klink, Gerard P. M.
Kapteijn, Freek
JOURNAL OF CATALYSIS, 2009, 261 (01) : 75 - 87
[50] Noble Gas Adsorption in Metal-Organic Frameworks Containing Open Metal Sites
Perry, John J.
Teich-McGoldrick, Stephanie L.
Meek, Scott T.
Greathouse, Jeffery A.
Haranczyk, Maciej
Allendorf, Mark D.
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (22): : 11685 - 11698

← 1 2 3 4 5 →