Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes

被引：69
|
作者：
McKeown, Bradley A. [1 ]
Foley, Nicholas A. [1 ]
Lee, John P. [1 ]
Gunnoe, T. Brent [1 ]
机构：
[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA
来源：
ORGANOMETALLICS | 2008年 / 27卷 / 16期
基金：
美国能源部;
关键词：
D O I：
10.1021/om8006008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Pt(II) complex [('bpy)Pt(Ph)(THF)][BAr'(4)] catalyzes the hydroarylation of olefins utilizing unactivated substrates. Preliminary studies indicate that the reactions proceed via Pt-mediated C-H activation rather than a traditional Friedel-Crafts pathway.
引用
收藏
页码：4031 / 4033
页数：3
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