Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes

被引:69
|
作者
McKeown, Bradley A. [1 ]
Foley, Nicholas A. [1 ]
Lee, John P. [1 ]
Gunnoe, T. Brent [1 ]
机构
[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA
基金
美国能源部;
关键词
D O I
10.1021/om8006008
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Pt(II) complex [('bpy)Pt(Ph)(THF)][BAr'(4)] catalyzes the hydroarylation of olefins utilizing unactivated substrates. Preliminary studies indicate that the reactions proceed via Pt-mediated C-H activation rather than a traditional Friedel-Crafts pathway.
引用
收藏
页码:4031 / 4033
页数:3
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