Interconversion of Quadruply and Quintuply Bonded Molybdenum Complexes by Reductive Elimination and Oxidative Addition of Dihydrogen

被引：38

作者：

Carrasco, Mario ^{[1
]}

Curado, Natalia ^{[1
]}

Maya, Celia ^{[1
]}

Peloso, Riccardo ^{[1
]}

Rodriguez, Amor ^{[1
]}

Ruiz, Eliseo ^{[2
,3
]}

Alvarez, Santiago ^{[2
,3
]}

Carmona, Ernesto ^{[1
]}

机构：

[1] Univ Seville, CSIC, Dept Quim Inorgan, Inst Invest Quim, Seville 41092, Spain

[2] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain

[3] Univ Barcelona, Inst Quim Teor & Computac, E-08028 Barcelona, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 11期

关键词：

density functional calculations; hydrides; metal arene; molybdenum; multiple bonds; METAL-METAL DISTANCES; TRANSITION-METAL; MULTIPLE BOND; MO-MO; CR; COORDINATION; TERPHENYL; CHEMISTRY; COMPOUND; TANTALUM;

D O I：

10.1002/anie.201209064

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five plus H2 gives four: UV irradiation of a bis(amidinate) complex with a [(H)Mo-Mo(H)] core induces reductive elimination of H2 and formation of a known quintuply bonded Mo-Mo species (see scheme) that reacts back with H2 to restore [(H)Mo-Mo(H)]. UV irradiation of the bis(hydride) species in benzene and toluene gives arene complexes in which the aromatic hydrocarbon bridges the molybdenum atoms. Dipp=2,6-diisopropylphenyl. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3227 / 3231

页数：5

共 50 条

[21] OXIDATIVE-ADDITION AND REDUCTIVE-ELIMINATION REACTIONS INVOLVING PLATINUM COMPLEXES AND TETRAORGANOTIN COMPOUNDS
EABORN, C
KUNDU, K
PIDCOCK, A
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (05): : 1223 - 1232
[22] Kinetic and mechanistic understanding of oxidative addition and reductive elimination of Pt(II) and Pt(IV) complexes
Love, Jennifer
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
[23] New molybdenum(V) complexes prepared by the oxidation of dinuclear quadruply-bonded molybdenum(II) monothiocarboxylates
Cindric, M
Matkovic-Calogovic, D
Vrdoljak, V
Kamenar, B
STRUCTURAL CHEMISTRY, 1998, 9 (05) : 353 - 358
[24] EFFECTS OF LIGAND AND METAL ON THE REDUCTIVE ELIMINATION OF DIHYDROGEN BY DINUCLEAR COMPLEXES OF CHROMIUM AND MANGANESE
BITTERWOLF, TE
RAGHUVEER, KS
INORGANICA CHIMICA ACTA, 1990, 172 (01) : 59 - 64
[25] 2,5-Dianilinoterephthalate bridged MM quadruply bonded complexes of molybdenum and tungsten
Chishohn, Malcolm H.
Patmore, Nathan J.
DALTON TRANSACTIONS, 2007, (01) : 91 - 96
[26] Reductive Elimination and Oxidative Addition of Hydrogen at Organostannylium and Organogermylium Cations
Diab, Fatima
Aicher, Frederik S. W.
Sindlinger, Christian P.
Eichele, Klaus
Schubert, Hartmut
Wesemann, Lars
CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (17) : 4426 - 4434
[27] MECHANISM OF OXIDATIVE ADDITION AND REDUCTIVE ELIMINATION AT A TUNGSTEN TRICARBONYL CENTER
PLEVA, J
POSS, MJ
BUFFIN, BP
RICHMOND, TG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 354 - INOR
[28] BIMETALLIC REACTIVITY - OXIDATIVE-ADDITION AND REDUCTIVE-ELIMINATION REACTIONS OF RHODIUM AND IRIDIUM BIMETALLIC COMPLEXES
SCHENCK, TG
MILNE, CRC
SAWYER, JF
BOSNICH, B
INORGANIC CHEMISTRY, 1985, 24 (15) : 2338 - 2344
[29] THE PREPARATION OF DIMOLYBDENUM(V,V) COMPLEXES FROM MOLYBDENUM QUADRUPLY BONDED METAL METAL DIMERS
DULEBOHN, JI
STAMATAKOS, TC
WARD, DL
NOCERA, DG
POLYHEDRON, 1991, 10 (23-24) : 2813 - 2820
[30] Photophysical Studies of Metal to Ligand Charge Transfer Involving Quadruply Bonded Complexes of Molybdenum and Tungsten
Chisholm, Malcolm H.
Brown-Xu, Samantha E.
Spilker, Thomas F.
ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (03) : 877 - 885

← 1 2 3 4 5 →