The Synthesis of Hexafluorosumanene and Its Congeners

被引：34
|
作者：
Schmidt, Bernd M. [1 ,3 ]
Topolinski, Berit [1 ,3 ]
Higashibayashi, Shuhei [1 ]
Kojima, Tatsuhiro [2 ]
Kawano, Masaki [2 ]
Lentz, Dieter [3 ]
Sakurai, Hidehiro [1 ]
机构：
[1] Inst Mol Sci, Res Ctr Mol Scale Nanosci, Okazaki, Aichi 4448787, Japan
[2] Pohang Univ Sci & Technol POSTECH, Div Adv Mat Sci, Pohang 790784, South Korea
[3] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 10期
关键词：
buckybowls; crystal engineering; fluorine; pi interactions; sumanene; GEM-DIFLUORO COMPOUNDS; ENANTIOSELECTIVE SYNTHESIS; SUMANENE; CORANNULENES; DERIVATIVES; BUCKYBOWL; TRIMETHYLSUMANENE; INVERSION; PACKING; BOWLS;
D O I：
10.1002/chem.201204622
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3282 / 3286
页数：5
相关论文
共 50 条
  • [21] NITRACRINE AND ITS CONGENERS - AN OVERVIEW
    GNIAZDOWSKI, M
    SZMIGIERO, L
    GENERAL PHARMACOLOGY, 1995, 26 (03): : 473 - 481
  • [22] SPANISH CANOA AND ITS CONGENERS
    TAYLOR, D
    INTERNATIONAL JOURNAL OF AMERICAN LINGUISTICS, 1957, 23 (03) : 242 - 244
  • [23] RENAL ONCOCYTOMA AND ITS CONGENERS
    BARNES, CA
    BECKMAN, EN
    AMERICAN JOURNAL OF CLINICAL PATHOLOGY, 1983, 79 (03) : 312 - 318
  • [24] AN IMPROVED SYNTHESIS OF PLANT-GROWTH REGULATING STEROID BRASSINOLIDE AND ITS CONGENERS
    KAMETANI, T
    KATOH, T
    FUJIO, J
    NOGIWA, I
    TSUBUKI, M
    HONDA, T
    JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (09): : 1982 - 1991
  • [25] Biotransformation of Silybin and its Congeners
    Kren, Vladimir
    Marhol, Petr
    Purchartova, Katerina
    Gabrielova, Eva
    Modriansky, Martin
    CURRENT DRUG METABOLISM, 2013, 14 (10) : 1009 - 1021
  • [26] SYNTHESIS OF MIMOCIN, AN ISOQUINOLINEQUINONE ANTIBIOTIC FROM STREPTOMYCES-LAVENDULAE, AND ITS CONGENERS
    KUBO, A
    KITAHARA, Y
    NAKAHARA, S
    IWATA, R
    NUMATA, R
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1988, 36 (11) : 4355 - 4363
  • [27] MOTHER + WORD AND ITS CONGENERS
    URDANG, L
    VERBATIM, 1976, 3 (03): : 6 - 7
  • [28] STRUCTURE OF GOYAZENSOLIDE AND ITS CONGENERS
    HERZ, W
    GOEDKEN, VL
    JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (14): : 2798 - 2800
  • [29] SPANISH HURACAN AND ITS CONGENERS
    不详
    INTERNATIONAL JOURNAL OF AMERICAN LINGUISTICS, 1956, 22 (04) : 275 - 276
  • [30] FRONTAL LEUCOTOMY AND ITS CONGENERS
    FREEMAN, W
    DISEASES OF THE NERVOUS SYSTEM, 1958, 19 (01): : 11 - 15
12345