The Synthesis of Hexafluorosumanene and Its Congeners

被引：34
|
作者：
Schmidt, Bernd M. [1 ,3 ]
Topolinski, Berit [1 ,3 ]
Higashibayashi, Shuhei [1 ]
Kojima, Tatsuhiro [2 ]
Kawano, Masaki [2 ]
Lentz, Dieter [3 ]
Sakurai, Hidehiro [1 ]
机构：
[1] Inst Mol Sci, Res Ctr Mol Scale Nanosci, Okazaki, Aichi 4448787, Japan
[2] Pohang Univ Sci & Technol POSTECH, Div Adv Mat Sci, Pohang 790784, South Korea
[3] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 10期
关键词：
buckybowls; crystal engineering; fluorine; pi interactions; sumanene; GEM-DIFLUORO COMPOUNDS; ENANTIOSELECTIVE SYNTHESIS; SUMANENE; CORANNULENES; DERIVATIVES; BUCKYBOWL; TRIMETHYLSUMANENE; INVERSION; PACKING; BOWLS;
D O I：
10.1002/chem.201204622
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3282 / 3286
页数：5
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