Efficient conversion of oxiranes to thiiranes with thiourea catalyzed with ruthenium trichloride and alumina

被引：17

作者：

Kazemi, F ^{[1
]}

Kiasat, AR ^{[1
]}

Ebrahimi, S ^{[1
]}

机构：

[1] Shahid Chamran Univ, Coll Sci, Dept Chem, Ahvaz, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 176卷

关键词：

oxirane; ruthenium trichloride; thiirane; thiourea;

D O I：

10.1080/10426500108055110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxiranes are efficiently converted to the corresponding thiiranes by thiourea in the presence of catalytic amounts of Ru(III) with excellent yields under mild and nonaqueous conditions. It is proved that the presence of Woelm chromatographic alumina in reaction media increases the rate of reactions.

引用

页码：135 / 140

页数：6

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