A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

被引：127
|
作者：
Yao, Qingxia [1 ]
Sun, Junliang [1 ]
Li, Kuo [2 ]
Su, Jie [1 ]
Peskov, Maxim V. [1 ]
Zou, Xiaodong [1 ]
机构：
[1] Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden
[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 14期
基金：
瑞典研究理事会;
关键词：
SORPTION PROPERTIES; HYDROGEN STORAGE; SURFACE-AREA; GAS-UPTAKE; COORDINATION; CATENATION; CATALYSIS; SITES; PORES; MOFS;
D O I：
10.1039/c2dt12088g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.
引用
收藏
页码：3953 / 3955
页数：3
相关论文
共 50 条
  • [31] Solvent-induced single-crystal to single-crystal transformation of a Zn4O-containing doubly interpenetrated metal-organic framework with a pcu net
    Lee, Jae Hwa
    Kim, Tae Kyung
    Suh, Myunghyun Paik
    Moon, Hoi Ri
    CRYSTENGCOMM, 2015, 17 (46): : 8807 - 8811
  • [32] Perspective Single-crystal metal-organic frameworks for electronic and opto-electronic devices
    Zhou, Kui
    Zhou, Yao
    Jia, Ziqi
    Ding, Guanglong
    Ma, Xin-Qi
    Niu, Wenbiao
    Yang, Sihan
    Han, Su-Ting
    Zhao, Jiyu
    Zhou, Ye
    CELL REPORTS PHYSICAL SCIENCE, 2023, 4 (11):
  • [33] Hierarchically porous metal-organic frameworks with single-crystal structures and their enhanced catalytic properties
    Zhang, Hang
    Huo, Jinhao
    Li, Jinqing
    Li, Feier
    Duan, Chongxiong
    Xi, Hongxia
    CRYSTENGCOMM, 2018, 20 (38): : 5754 - 5759
  • [34] Single-crystal to single-crystal transformations in discrete solvated metallocycles: the role of the metal ion
    Jacobs, Tia
    Barbour, Leonard J.
    NEW JOURNAL OF CHEMISTRY, 2013, 37 (01) : 71 - 74
  • [35] Single-Crystal to Single-Crystal Cross-Linking of an Interpenetrating Chiral Metal-Organic Framework and Implications in Asymmetric Catalysis
    Ma, Liqing
    Wu, Chuan-De
    Wanderley, Marcela M.
    Lin, Wenbin
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (44) : 8244 - 8248
  • [36] A Single-Crystal Open-Capsule Metal-Organic Framework
    Wei, Yong-Sheng
    Zhang, Mei
    Kitta, Mitsunori
    Liu, Zheng
    Horike, Satoshi
    Xu, Qiang
    Journal of the American Chemical Society, 2019,
  • [37] Octahedral to Tetrahedral Conversion upon a Ligand-Substitution-Induced Single-Crystal to Single-Crystal Transformation in a Rectangular Zn(II) Metal-Organic Framework and Its Photocatalysis
    Chimupala, Yothin
    Kaeosamut, Nippich
    Yimklan, Saranphong
    CRYSTAL GROWTH & DESIGN, 2021, 21 (09) : 5373 - 5382
  • [38] Dynamic behavior of macrocycle-based organic frameworks in single-crystal to single-crystal guest exchanges
    Tominaga, Masahide
    Shinkawa, Shoyo
    Hyodo, Tadashi
    Yamaguchi, Kentaro
    CRYSTENGCOMM, 2021, 23 (40) : 7039 - 7043
  • [39] Direct Guest Exchange Induced Single-Crystal to Single-Crystal Transformation Accompanying Irreversible Crystal Expansion in Soft Porous Coordination Polymers
    Ho, Tzu-Yan
    Huang, Sheng-Ming
    Wu, Jing-Yun
    Hsu, Kung-Chung
    Lu, Kuang-Lieh
    CRYSTAL GROWTH & DESIGN, 2015, 15 (09) : 4266 - 4271
  • [40] ION-EXCHANGE REACTIONS ON PERISTERITES WITH DETAILED OBSERVATIONS ON THEIR POWDER CRYSTAL AND SINGLE-CRYSTAL PHOTOGRAPHS
    VISWANATHAN, K
    CONTRIBUTIONS TO MINERALOGY AND PETROLOGY, 1973, 41 (02) : 145 - 150
12345