Bis[bis(triphenylphosphoranylidene)-ammonium] μ-tetrathiaoxalato-bis[(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(II)]

被引：4

作者：

Geiser, U

Mercuri, ML

Parakka, JP

机构：

[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

[3] Univ Cagliari, Dipartimento Chim & Tecnol Inorgan & Met Organ, I-09124 Cagliari, Italy

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199004692

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The binuclear complex anion in [(C6H5)(6)P2N](2)[(C3S5)Ni(C2S4)Ni(C3S5)], conventionally abbreviated (PPN)(2)[(dmit)Ni(tto)Ni(dmit)], where PPN is bis(triphenylphosphoranylidene)ammonium, dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate and tto is tetrathiaoxalate, is centrosymmetric and essentially planar, except for a small twist of 2.7(1)degrees at the Ni centers. The bond lengths [average Ni-S distance 2.166(8) Angstrom] and angles are comparable to those reported elsewhere for other salts of the component ions. The crystal packing and the charge state of the complex anion are not favorable for electrical conduction. The binuclear complex anion was synthesized by a simpler method than that published previously.

引用

页码：1253 / 1255

页数：3

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