Preparation, Characterisation and Use of [(N-Bu2Sn)S2N2]2 as a Metathetical Reagent

被引：1

作者：

Aucott, Stephen Mark ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Woollins, J. Derek ^{[1
]}

机构：

[1] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 169卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

Tin; Sulfur; Nitrogen; Metathesis; Metallacycles;

D O I：

10.1080/10426500108546632

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric compound [(n-Bu2Sn)S2N2](2) is readily prepared by addition of (n-)Bu(2)Sncl(2) to a liquid ammonia/[S4N3][Cl] reaction mixture. Reaction of [n-Bu2SnS2N2](2) with mono and dimeric organometallic M(III) (M = Rh, Ir) complexes bearing Cp* ligands (Cp* = 1,2,3.4,5-pentamethylcyclopentadienyl) and M(II) (M = Ru, Os) phosphine complexes containing a cis arrangement of chlorides gives compounds with MS2N2 metallacycles.

引用

页码：235 / 238

页数：4

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