Magnetic Silica-Supported Ruthenium Nanoparticles: An Efficient Catalyst for Transfer Hydrogenation of Carbonyl Compounds

被引：106

作者：

Baig, R. B. Nasir ^{[1
]}

Varma, Rajender S. ^{[1
]}

机构：

[1] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2013年 / 1卷 / 07期

关键词：

Green synthesis; Magnetic silica; Ruthenium nanoparticles; Transfer hydrogenation; Microwave irradiation; ASYMMETRIC TRANSFER HYDROGENATION; MEERWEIN-PONNDORF-VERLEY; ASSISTED ORGANIC-SYNTHESIS; CHEMOSELECTIVE REDUCTION; AQUEOUS-MEDIUM; KETONES; MICROWAVE; ZEOLITE; BETA; NANOCATALYSTS;

D O I：

10.1021/sc400032k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot synthesis of ruthenium nanoparticles on magnetic silica is described, which involves in situ generation of magnetic silica (Fe3O4@ SiO2) and ruthenium nanoparticle immobilization. The transfer hydrogenation of carbonyl compounds occurs in high yield along with excellent selectivity using this catalyst under microwave irradiation conditions.

引用

页码：805 / 809

页数：5

共 50 条

[21] Cyclometalated Dicarbonyl Ruthenium Catalysts for Transfer Hydrogenation and Hydrogenation of Carbonyl Compounds
Giboulot, Steven
Baldino, Salvatore
Ballico, Maurizio
Nedden, Hans Gunter
Zuccaccia, Daniele
Baratta, Walter
ORGANOMETALLICS, 2018, 37 (13) : 2136 - 2146
[22] One-pot synthesis of porous silica-supported ultrafine Ni nanoparticles as efficient and stable catalyst for selective hydrogenation of benzophenone
Qiao, Xianliang
She, Tiantian
Zhang, Huiling
Wen, Xin
Niu, Libo
Ricardez-Sandoval, Luis
Li, Jingde
Bai, Guoyi
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 259
[23] A simple and reproducible method for the synthesis of silica-supported rhodium nanoparticles and their investigation in the hydrogenation of aromatic compounds
Mevellec, Vincent
Nowicki, Audrey
Roucoux, Alain
Dujardin, Christophe
Granger, Pascal
Payen, Edmond
Philippot, Karine
NEW JOURNAL OF CHEMISTRY, 2006, 30 (08) : 1214 - 1219
[24] Ruthenium nanoparticles supported on zeolite Y as an efficient catalyst for selective hydrogenation of xylose to xylitol
Mishra, Dinesh Kumar
Dabbawala, Aasif Asharaf
Hwang, Jin-Soo
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 376 : 63 - 70
[25] Mesoporous silica-supported Pd nanoparticles; Highly selective catalyst for hydrogenation of olefins in supercritical carbon dioxide
Lee, Seoung-Soo
Park, Byoung-Kyu
Byeon, Song-Ho
Chang, Fei
Kim, Hakwon
CHEMISTRY OF MATERIALS, 2006, 18 (24) : 5631 - 5633
[26] CARBON MONOXIDE HYDROGENATION OVER SILICA-SUPPORTED RHODIUM CARBONYL CLUSTER CATALYSTS
ZHANG Bing-Kai CHEN Lin-Feng GUO Ting-Huang LAN Hua-Shui Fujian Institute of Research on the
Journal of Natural Gas Chemistry , 1992, (03) : 200 - 213
[27] INSITU INFRARED STUDY OF CO HYDROGENATION OVER SILICA AND ALUMINA-SUPPORTED RUTHENIUM AND SILICA-SUPPORTED IRON
KING, DL
JOURNAL OF CATALYSIS, 1980, 61 (01) : 77 - 86
[28] Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica
Li, Jun
Zhang, Yanmei
Han, Difei
Gao, Qiang
Li, Can
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 298 (1-2) : 31 - 35
[29] An Acylthiourea Ligated Fe(II) Complex on Silica Nanoparticles for Transfer Hydrogenation of Carbonyl Compounds
Sindhuja, Dharmalingam
Vasanthakumar, Punitharaj
Bhuvanesh, Nattamai S. P.
Karvembu, Ramasamy
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (43) : 14386 - 14393
[30] Efficient transfer hydrogenation of nitro compounds over a magnetic palladium catalyst
Jiang, Liang
Zhang, Zehui
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (48) : 22983 - 22990

← 1 2 3 4 5 →