Growth and characterization of non-linear optical crystal Cd3Zn3B4O12

被引：6
|
作者：
Zhang, Fan [1 ]
Shen, Dezhong [1 ]
Shen, Guangqiu [1 ]
Wang, Xiaoqing [1 ]
机构：
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
来源：
MATERIALS RESEARCH BULLETIN | 2008年 / 43卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Optical material; Inorganic compounds; Crystal growth; Optical properties;
D O I：
10.1016/j.materresbull.2008.08.016
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Cd3Zn3B4O12 polycrystals were synthesized by solid-state and wet chemical reaction methods. Cd3Zn3B4O12 single crystals with millimeter grade were grown from the self-flux B2O3 (Cd:Zn:B = 1: 1: 1.5); and larger crystals were obtained from the PbO-0.85PbF(2) fluxes easily. As-grown crystals were characterized by differential scanning calorimetry and thermogravimetric, X-ray diffraction, infrared and Raman spectral analysis, respectively. The non-linear optical coefficient of the Cd3Zn3B4O12 crystal is 2.6 times as large as that of KH2PO4 crystal. Chemical etching shows that this crystal is very stable in neutral solution and not hygroscopic in air at room temperature. Crown Copyright (c) 2008 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：3188 / 3194
页数：7
相关论文
共 50 条
  • [1] A non-linear optical crystal, Cd3Zn3(BO3)4
    Sun, TQ
    Pan, F
    Wang, RJ
    Shen, GQ
    Wang, XQ
    Shen, DZ
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : I107 - I108
  • [2] Growth and characterization of non-linear optical crystal ZnCd(SCN)4
    Joseph, G. P.
    Rajarajan, K.
    Vimalan, M.
    Thomas, P. C.
    Madhavan, J.
    Kumar, S. M. Ravi
    Mohamed, M. Gulam
    Mani, G.
    Sagayaraj, P.
    CRYSTAL RESEARCH AND TECHNOLOGY, 2007, 42 (03) : 247 - 252
  • [3] 助熔剂法生长非线性光学晶体Cd3Zn3B4O12及其性质研究（英文）
    焦志伟
    张文林
    沈德忠
    王晓青
    沈光球
    人工晶体学报, 2010, 39 (06) : 1353 - 1358
  • [4] Growth and characterization of semiorganic non-linear optical LHB single crystal
    Ittyachan, R
    Thomas, PC
    Anand, DP
    Palanichamy, M
    Sagayaraj, P
    MATERIALS CHEMISTRY AND PHYSICS, 2005, 93 (2-3) : 272 - 276
  • [5] Polarised infrared and Raman studies of YCa4O(BO3)3 a non-linear optical single crystal
    Krishnakumar, V
    Nagalakshmi, R
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2004, 60 (12) : 2733 - 2739
  • [6] Synthesis, growth and characterization of magnesium sulphamate - A promising non-linear optical crystal
    Jaishree, D.
    Kanchana, G.
    Kesavasamy, R.
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2015, 53 (06) : 404 - 408
  • [7] Crystal Growth and Characterization of Non-linear Optical L-tyrosine Chloride
    Dharmaprakash, Sampyady M.
    Moolya, B. Narayana
    Jayarama, A.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2005, 61 : C438 - C438
  • [8] Investigation on the crystal growth and characterization of an organometallic non-linear optical crystal - Antimony potassium tartrate
    Merline, G. K. Priya
    Chitra, M.
    Krishnan, P.
    OPTIK, 2015, 126 (24): : 5339 - 5341
  • [9] Growth and characterization of CaCu3Ru4O12 single crystal
    Wang Rong-Juan
    Zhu Yuan-Yuan
    Li, Wang
    Yong, Liu
    Jing, Shi
    Rui, Xiong
    Wang Jun-Feng
    CHINESE PHYSICS B, 2015, 24 (09)
  • [10] Growth and characterization of CaCu3Ru4O12 single crystal
    王蓉娟
    朱媛媛
    王理
    刘雍
    石兢
    熊锐
    王俊峰
    Chinese Physics B, 2015, 24 (09) : 506 - 511
12345